HRID431157

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID136603

Benzene, 1-bromo-4-ethynyl-

C8H5Br

HCID580759

2-Chlorobenzenemethanethiol

C7H7ClS

HCID5360545

Sodium

PRODUCTS

生成物

$结构：Clc1ccccc1C(/C=C\c1ccc(Br)cc1)SC(/C=C\c1ccc(Br)cc1)c1ccccc1Cl$

HCID86588946

未命名化合物

PROCEDURE

实验过程

A solution of 4-bromophenylacetylene (0.02 mol) and 2-chlorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-bromostyryl 2-chlorobenzylsulfide. The title compound was obtained in 84% yield following oxidation. 1HNMR (CDC13) δ4.57 (2H, s), 6.70 (1H, d, JH,H=11.58), 7.18-7.58 (8H aromatic+1H ethylenic).