HRID431160

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID13018

Benzene, 1-ethynyl-4-methyl- (9CI)

C9H8

HCID580759

2-Chlorobenzenemethanethiol

C7H7ClS

HCID5360545

Sodium

PRODUCTS

生成物

$结构：Cc1ccc(/C=C\C(SC(/C=C\c2ccc(C)cc2)c2ccccc2Cl)c2ccccc2Cl)cc1$

HCID86588949

未命名化合物

PROCEDURE

实验过程

A solution of 4-methylphenylacetylene (0.02 mol) and 2-chlorobenzyl mercaptan (0.02 mol) and metallic sodium (0.02 g atom) was subjected to Procedure 2 to form (Z)-4-methylstyryl 2-chlorobenzylsulfide. The title compound was obtained in 76% yield following oxidation. 1HNMR (CDC13) δ2.50 (3H, s), 4.58 (2H, s), 6.80 (1H, d, JH,H=11.88), 7.20-7.63 (9H aromatic+1H ethylenic).