Methane → (2Z)-4-(Dodecylamino)-4-oxo-2-butenoic acid

HRID 431404Notes

Reaction equation

HRID 431404 reaction equation
[CH2:1]([NH:13][C:14](=[O:20])/[CH:15]=[CH:16]\[C:17]([OH:19])=[O:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].C(N)(=O)/C=C\C(O)=O.C>C1(C)C=CC=CC=1>[CH2:1]([NH:13][C:14](=[O:20])/[CH:15]=[CH:16]\[C:17]([OH:19])=[O:18])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12]

Participants

4

Reactant 2

HCID 297MethaneHCID 86759289HCID 86759289, compound

Product 1

HCID 5356956(2Z)-4-(Dodecylamino)-4-oxo-2-butenoic acid

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

2 g maleic acid amide N-dodecylmaleic acid amide are dissolved in 150 ml toluene and compounded with 10 g black (FW 1 or Printex Alpha). The suspension is boiled four hours under reflux and then drawn off, washed with acetone and dried eight hours in a drying oven at 105° C. The resulting black carries dodecyl groups.

Workup

  1. temperatureunder reflux
  2. washwashed with acetone
  3. customdried eight hours in a drying oven at 105° C

Sources & evidence

ORD record
ord-bb99cb162650402781f747fda65ff5fd
Source dataset
uspto-grants-2003_12
Patent number
US06660075B2

Reaction notes

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