Di-tert-butyl peroxide → HCID 18760573, compound

HRID 432888Notes

Reaction equation

HRID 432888 reaction equation
[CH3:1][CH:2]([O:9][N:10]1[C:15]([CH3:17])([CH3:16])[CH2:14][O:13][C:12](=[O:18])[C:11]1([CH2:20][CH3:21])[CH3:19])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[C:22](OOC(C)(C)C)(C)(C)C>C(C1C=CC=CC=1)C>[CH3:1][CH:2]([O:9][N:10]1[C:15]([CH3:16])([CH3:17])[CH2:14][O:13][C:12](=[O:18])[C:11]1([CH2:19][CH3:22])[CH2:20][CH3:21])[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1

Participants

4

Reactant 2

HCID 8033Di-tert-butyl peroxideHCID 18760512HCID 18760512, compound

Product 1

HCID 18760573HCID 18760573, compoundYield 52%

Reagents, catalysts & solvents 1

HCID 7500EthylbenzeneSolvent

Procedure

In analogy to Example B3, compound (206), 4.75 g (0.026 mol) of 3,3-diethyl-5,5-dimethylmorpholin-2-on-4-oxyl are reacted with t-butylperoxide and ethylbenzene as solvent, resulting in 4.1 g (52%) of compound (210) in the form of a colourless oil.

Sources & evidence

ORD record
ord-9be1b1d065e140bba2b8e5319a6d95b1
Source dataset
uspto-grants-2003_12
Patent number
US06664353B2

Reaction notes

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