Pentane → HCID 131720369, compound

HRID 434117Notes

Reaction equation

HRID 434117 reaction equation
[CH3:1][CH:2]1[C:6]([Si:7]([NH:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=2[O:17][CH3:18])([CH3:9])[CH3:8])=[C:5](C)[C:4]([CH3:20])=[C:3]1[CH3:21].[CH2:22]([Li:26])CCC.[CH3:27]CCCC>C(OCC)C.CCCCCC>[CH3:20][C:4]1[C:3]([CH3:21])=[C:2]([CH3:1])[C:6]([Si:7]([N-:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=2[O:17][CH3:18])([CH3:8])[CH3:9])([CH3:22])[CH:5]=1.[Li+:26].[Li+:26].[CH3:20][C:4]1[C:3]([CH3:21])=[C:2]([CH3:1])[C:6]([Si:7]([N-:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][C:12]=2[O:17][CH3:18])([CH3:8])[CH3:9])([CH3:27])[CH:5]=1

Participants

6

Reactant 3

HCID 8003PentaneHCID 22494451HCID 22494451, compoundHCID 178418339Butyllithium

Product 1

HCID 131720369HCID 131720369, compound

Reagents, catalysts & solvents 2

HCID 3283Diethyl EtherSolventHCID 8058HexaneSolvent

Procedure

To 1.4 g (4.6 mmol) ((tetramethylcyclopenta-dienyl)dimethylsilyl)(2-methoxyphenyl)amine in diethyl ether was added dropwise 3.9 mL of 2.5 M butyl lithium (9.8 mmol) in hexane solvent. A white precipitate formed. Pentane was added to the mixture. The slurry was filtered and the solids washed with pentane.

Workup

  1. customA white precipitate formed
  2. filtrationThe slurry was filtered
  3. washthe solids washed with pentane

Sources & evidence

ORD record
ord-217998dde46b445fa94b2db263dc9d6b
Source dataset
uspto-grants-2003_12
Patent number
US06670432B1

Reaction notes

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