HRID434739

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCCCC[C@@H](/C=C/[C@@H]1[C@H]2CC(CCCCC(=O)OC)O[C@H]2C[C@H]1OC1CCCCO1)OC1CCCCO1

HCID86738982

未命名化合物

PRODUCTS

生成物

结构：CCCCC[C@H](O)/C=C/[C@@H]1[C@H]2CC(CCCCC(=O)OC)O[C@H]2C[C@H]1O

HCID70595130

未命名化合物

收率 73.7%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID176

Acetic Acid

C2H4O2

溶剂HCID8028

Tetrahydrofuran

C4H8O

PROCEDURE

实验过程

By proceeding as described in Example 2 but using 435 mg of (13E)-(6RS,9α,11α,15S)-6,9-epoxy-11,15-bis-(tetrahydropyran-2-yloxy)prost-13-enoic acid methyl ester (prepared as described in Example 5) dissolved in a mixture of 0.7 ml of tetrahydrofuran and 9 ml of 65% aqueous acetic acid, there were obtained 220 mg of the title compound having the following physical characteristics: