Hydrochloric Acid → HCID 13599060, compound

HRID 434821Notes

Reaction equation

HRID 434821 reaction equation
[F:1][C:2]([F:18])([F:17])C1C=CC=CC=1C(O[Si](C)(C)C)C#N.Cl.[OH:20][CH:21]([C:27]1[CH:32]=[CH:31][CH:30]=[CH:29][C:28]=1C(F)(F)F)[C:22](=[NH:26])[O:23][CH2:24][CH3:25]>>[OH:20][CH:21]([C:27]1[CH:28]=[CH:29][CH:30]=[C:31]([C:2]([F:18])([F:17])[F:1])[CH:32]=1)[C:22](=[NH:26])[O:23][CH2:24][CH3:25]

Participants

4

Reactant 3

HCID 313Hydrochloric AcidHCID 13599056HCID 13599056, compoundHCID 13854741HCID 13854741, compound

Product 1

HCID 13599060HCID 13599060, compound

Procedure

By the procedures of Examples 2 and 11 (Method A) 2-(2-trifluoromethylphenyl)-2-trimethylsiloxyethanenitrile (15.5 g.) in 500 ml. of saturated ethanolic hydrogen chloride was converted to ethyl 1-hydroxy-1-(3-trifluoromethylphenyl)methanecarboximidate [9.6 g., 70%; m/e 247; ir (KBr) 1661, 1389, 1333, 1305, 1163, 1117 cm-1 ].

Sources & evidence

ORD record
ord-8d15782b54d647ffb8e2212ca3a7be82
Source dataset
uspto-grants-1983_08
Patent number
US04399296

Reaction notes

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