Nitric Acid → HCID 20490891, compound

HRID 435121Notes

Reaction equation

HRID 435121 reaction equation
[CH2:1]([O:4][CH:5]([C:12]1[CH:17]=[CH:16][C:15]([Cl:18])=[CH:14][C:13]=1[Cl:19])[CH2:6][N:7]1[CH:11]=[N:10][CH:9]=[N:8]1)[CH:2]=[CH2:3].[N+:20]([O-:23])([OH:22])=[O:21]>C(Cl)(Cl)Cl>[N+:20]([O-:23])([OH:22])=[O:21].[CH2:1]([O:4][CH:5]([C:12]1[CH:17]=[CH:16][C:15]([Cl:18])=[CH:14][C:13]=1[Cl:19])[CH2:6][N:7]1[CH:11]=[N:10][CH:9]=[N:8]1)[CH:2]=[CH2:3]

Participants

4

Reactant 2

HCID 944Nitric AcidHCID 13655422HCID 13655422, compound

Product 1

HCID 20490891HCID 20490891, compoundYield 95%

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

29.5 g (0.1 mole) of 1-(2',4'-dichlorophenyl)-2-(1,2,4-triazol-1-yl)-ethyl allyl ether were dissolved in 200 ml of chloroform and 6.4 g of 95% strength nitric acid were added. The crystallization of the salt was completed by adding 250 ml of ether. After filtering off and drying, 34 g (95% of theory) of 1-(2',4'-dichlorophenyl)-2-(1,2,4-triazol-1-yl)-ethyl allyl ether nitrate of melting point 131° C. were obtained.

Workup

  1. customThe crystallization of the salt
  2. additionby adding 250 ml of ether
  3. filtrationAfter filtering off
  4. customdrying

Sources & evidence

ORD record
ord-3f1f9cd3f97446b3880ce6187833e492
Source dataset
uspto-grants-1983_08
Patent number
US04400388

Reaction notes

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