HRID435180

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID2326685

未命名化合物

HCID67418806

未命名化合物

PRODUCTS

生成物

结构：O=C1C2C=CCCC2C(=O)N1CCOC(OCCN1C(=O)C2C=CCCC2C1=O)(C(=O)c1ccccc1)c1ccccc1

HCID20440919

未命名化合物

收率 87.6%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6228

N,N-Dimethylformamide

C3H7NO

PROCEDURE

实验过程

Benzil-di-(β-bromoethyl)ketal (13.26 g) and 11.42 g of sodium 1,2,5,6-tetrahydrophthalimide were dissolved in 100 ml of N,N-dimethylformamide, and reacted and worked up in the same way as in Example 4. There was obtained 15.3 g (yield 85.9%) of benzil-di-(β-1,2,5,6-tetrahydrophthalimidoethyl)ketal.

WORKUP

后处理

customreacted

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-8b7ce976d45e46eaafc12c8062545054
来源数据集: uspto-grants-1983_08
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04400519
来源说明: uspto-grants-1983_08

反应 SMILES

Br[CH2:2][CH2:3][O:4][C:5]([O:20][CH2:21][CH2:22]Br)([C:12]([C:14]1[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=1)=[O:13])[C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1.[C:24]1(=[O:34])[NH:28][C:27](=[O:29])[CH:26]2[CH:30]=[CH:31][CH2:32][CH2:33][CH:25]12.[Na]>CN(C)C=O>[C:24]1(=[O:34])[N:28]([CH2:2][CH2:3][O:4][C:5]([O:20][CH2:21][CH2:22][N:28]2[C:27](=[O:29])[CH:26]3[CH:30]=[CH:31][CH2:32][CH2:33][CH:25]3[C:24]2=[O:34])([C:12]([C:14]2[CH:19]=[CH:18][CH:17]=[CH:16][CH:15]=2)=[O:13])[C:6]2[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=2)[C:27](=[O:29])[CH:26]2[CH:30]=[CH:31][CH2:32][CH2:33][CH:25]12