huagongshe.com
HRID435238

反应详情

EQUATION

反应方程式

HRID 435238 的结构方程式

REACTANTS

反应物

3
结构：CC(C)I
HCID6362

2-Iodopropane

C3H7I

结构：O=C([O-])[O-].[K+].[K+]
HCID11430

Potassium Carbonate

CK2O3

结构：CCOC(=O)C(=NO)C(C)=O
HCID178472877

未命名化合物

PRODUCTS

生成物

1
结构：CCOC(=O)C(=NOC(C)C)C(C)=O
HCID539498

Butanoic acid, 2-[(1-methylethoxy)imino]-3-oxo-, ethyl ester, (Z)-

C9H15NO4

收率 93.3%

AUXILIARIES

试剂、催化剂与溶剂

1
结构：CC(C)=O
溶剂HCID180

Acetone

C3H6O

PROCEDURE

实验过程

Ethyl 2-hydroxyimino-3-oxobutyrate (syn isomer, 30 g.), iso-propyl iodide (32.5 g.), potassium carbonate (39.5 g.) and acetone (150 ml.) were treated in a similar manner to that of Example D-(1) to give ethyl 2-iso-propoxyimino-3-oxobutyrate (syn isomer, 35.4 g.), oil.