HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → HCID 12232363, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Sodium borohydride | HCID 4311764 | — |
| Reactant | HCID 12232358 | HCID 12232358 | — |
| Solvent | Ethanol | HCID 702 | — |
| Product | HCID 12232363 | HCID 12232363 | — |
Reaction Steps
50 g of 2-bromo- 10,11-dihydro-dibenzo[b,f]thiepin-10-one are dispersed in 250 ml of ethanol, treated with 9.9 g of sodium borohydride and stirred for 1 hour. After the addition of water, the mixture is extracted with ether. The organic phase is washed with water, dried over magnesium sulphate and evaporated. There is obtained 2-bromo- 10,11-dihydro-dibenzo-[b,f]thiepin-10-ol of melting point 108°-110° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04006145 |
| Source dataset | uspto-grants-1977_02 |
| ORD ID | ord-a009f61a41b84c809b6293bf5b113633 |
| Source note | uspto-grants-1977_02 |