HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrochloric Acid → HCID 15619006, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrochloric Acid | HCID 313 | — |
| Reactant | Calcium Chloride | HCID 5284359 | — |
| Reactant | 10,11-Dihydro-2-trifluoromethyl-dibenzo[b,f]thiepin-10-ol | HCID 12223973 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | HCID 15619006 | HCID 15619006 | — |
Reaction Steps
11.4 g of 10,11-dihydro-2-trifluoromethyl-dibenzo[b,f]thiepin-10-ol, 100 ml of benzene and 4 g of calcium chloride are saturated with hydrochloric acid gas for 2 hours at 15° C and subsequently stirred at room temperature for 3 hours. The mixture is filtered and concentrated under reduced pressure. There is obtained 10-chloro-10,11-dihydro-2-trifluoromethyl-dibenzo[b,f]thiepin in the form of yellow crystals.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04006144 |
| Source dataset | uspto-grants-1977_02 |
| ORD ID | ord-50274431c84646888f15669669bbca86 |
| Source note | uspto-grants-1977_02 |