Sodium Methoxide → HCID 178514233, compound

HRID 435738Notes

Reaction equation

HRID 435738 reaction equation
[NH:1]1[CH:5]=[N:4][C:3]([C:6]([NH2:8])=[O:7])=[N:2]1.C[O-].[Na+:11]>CO>[Na+:11].[NH:1]1[CH:5]=[N:4][C:3]([C:6]([NH-:8])=[O:7])=[N:2]1

Participants

4

Reactant 2

HCID 10942334Sodium MethoxideHCID 178513825HCID 178513825, compound

Product 1

HCID 178514233HCID 178514233, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

A 0.6 g. portion of 1,2,4-triazole-3-carboxamide is added to 5.4 ml. of a solution of 1N sodium methoxide in methanol contained in a test tube at room temperature. The mixture is shaken vigorously. Within about 1/2 to one minute most of the solid dissolves. The mixture is quickly filtered through a sintered glass funnel with vacuum. The light yellow filtrate is allowed to stand and deposits a colorless solid. A portion of methanol is added and the solid is collected, washed with methanol and air dried for one hour yielding 0.3 g. of product.

Workup

  1. dissolutionWithin about 1/2 to one minute most of the solid dissolves
  2. filtrationThe mixture is quickly filtered through a sintered glass funnel with vacuum
  3. additionA portion of methanol is added
  4. customthe solid is collected
  5. washwashed with methanol and air
  6. customdried for one hour
  7. customyielding 0.3 g

Sources & evidence

ORD record
ord-2a4b944f84a5495a8fa97659ba1eab16
Source dataset
uspto-grants-1977_02
Patent number
US04006159

Reaction notes

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