HRID435851

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID702

Ethanol

C2H6O

HCID516892

Sodium Bicarbonate

CHNaO3

结构：CC(C)(C)c1ccccc1OCC(O)COc1cccc2c(=O)cc(C(=O)O)oc12

HCID13090988

未命名化合物

PRODUCTS

生成物

结构：CC(C)(C)c1ccccc1OCC(O)COc1cccc2c(=O)cc(C(=O)[O-])oc12.CC(C)(C)c1ccccc1OCC(O)COc1cccc2c(=O)cc(C(=O)[O-])oc12.O.O.O.[Na+].[Na+]

HCID131710631

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID962

Water

H2O

PROCEDURE

实验过程

To a hot solution of 4.328 parts of 8-(3 -2-t-butylphenoxy -2-hydroxypropoxy)-4-oxo-4H-1-benzopyran-2carboxylic acid in 250 parts of ethanol was added a solution of 0.882 parts of sodium bicarbonate in 50 parts of water. The resulting solution was filtered and allowed to cool to give 4.0 parts of sodium 8-(3-[2-t-butylphenoxy]-2-hydroxypropoxy)-4-oxo-4H-1-benzopyran-2-carboxylate sesquihydrate after collecting and drying over phosphorus pentoxide.

WORKUP

后处理

filtrationThe resulting solution was filtered
temperatureto cool

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-5e3df06ed419490cbc37d510ea3623bd
来源数据集: uspto-grants-1977_02
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04006245
来源说明: uspto-grants-1977_02

反应 SMILES

[C:1]([C:5]1[CH:30]=[CH:29][CH:28]=[CH:27][C:6]=1[O:7][CH2:8][CH:9]([OH:26])[CH2:10][O:11][C:12]1[C:21]2[O:20][C:19]([C:22]([OH:24])=[O:23])=[CH:18][C:17](=[O:25])[C:16]=2[CH:15]=[CH:14][CH:13]=1)([CH3:4])([CH3:3])[CH3:2].C([OH:33])C.C(=O)(O)[O-:35].[Na+:38]>O>[OH2:7].[C:1]([C:5]1[CH:30]=[CH:29][CH:28]=[CH:27][C:6]=1[O:7][CH2:8][CH:9]([OH:26])[CH2:10][O:11][C:12]1[C:21]2[O:20][C:19]([C:22]([O-:24])=[O:23])=[CH:18][C:17](=[O:25])[C:16]=2[CH:15]=[CH:14][CH:13]=1)([CH3:4])([CH3:2])[CH3:3].[Na+:38].[OH2:33].[OH2:35].[Na+:38].[C:1]([C:5]1[CH:30]=[CH:29][CH:28]=[CH:27][C:6]=1[O:7][CH2:8][CH:9]([OH:26])[CH2:10][O:11][C:12]1[C:21]2[O:20][C:19]([C:22]([O-:24])=[O:23])=[CH:18][C:17](=[O:25])[C:16]=2[CH:15]=[CH:14][CH:13]=1)([CH3:4])([CH3:2])[CH3:3]