Benzoyl chloride → N'-tert-butylbenzohydrazide

HRID 435946Notes

Reaction equation

HRID 435946 reaction equation
[C:1](Cl)(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:10]([NH:14][NH2:15])([CH3:13])([CH3:12])[CH3:11].C(NNC(C)(C)C)(=O)C(C)(C)C>O>[C:1]([NH:15][NH:14][C:10]([CH3:13])([CH3:12])[CH3:11])(=[O:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 7412Benzoyl chlorideHCID 81890tert-ButylhydrazineHCID 22613473HCID 22613473, compound

Product 1

HCID 299436N'-tert-butylbenzohydrazideYield 71%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

1-benzoyl-2tert.-butylhydrazine was prepared in 71% yield by adding benzoyl chloride to a basic solution of t-butylhydrazine in water. The procedure was the same as that for preparing 1-pivaloyl-2-tert.-butylhydrazine in Example XIX A. The product has a melting range of 94° - 95° C. and its infra-red spectrum was consistent with that of the proposed structure.

Sources & evidence

ORD record
ord-76474f50e82a4fb0a6d27137e756ce6b
Source dataset
uspto-grants-1977_02
Patent number
US04007165

Reaction notes

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