Benzene → HCID 21455210、化合物

HRID 436205ノート

反応式

HRID 436205 の反応式
[OH:1][C:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([C:14]=2[OH:16])=[C:12]([OH:17])[CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1.[CH:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1.[O:24]([C:31]1[CH:39]=[CH:38][CH:37]=[CH:36][C:32]=1[C:33](Cl)=[O:34])[C:25]1[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=1>N1C=CC=CC=1>[O:1]([C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][C:15]=1[C:14]([O:1][C:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([C:14]=2[O:16][C:33](=[O:34])[C:32]2[CH:36]=[CH:37][CH:38]=[CH:39][C:31]=2[O:24][C:25]2[CH:30]=[CH:29][CH:28]=[CH:27][CH:26]=2)=[C:12]([O:17][C:33](=[O:34])[C:32]2[CH:36]=[CH:37][CH:38]=[CH:39][C:31]=2[O:24][C:25]2[CH:26]=[CH:27][CH:28]=[CH:29][CH:30]=2)[CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1)=[O:16])[C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1

参加物

5

反応物 3

HCID 241BenzeneHCID 101871,8,9-AnthracenetriolHCID 110753032-Phenoxybenzoyl chloride

生成物 1

HCID 21455210HCID 21455210、化合物

試薬・触媒・溶媒 1

HCID 1049Pyridine溶媒

実験手順

1,8,9-Trihydroxyanthracene (4 g.), benzene (125 ml.) and pyridine (12 g.) were stirred under nitrogen until a clear solution resulted. 2-Phenoxybenzoyl chloride (17 g.) was added and the mixture was stirred for 2 hours, filtered and evaporated under reduced pressure to a thick oil. This was dissolved in toluene and the solution was added dropwise with stirring to petroleum ether (b.p. 40°-60° C.) to yield a pale yellow-green solid (13 g., 90%), m.p. 110° C.

後処理

  1. customresulted
  2. filtrationfiltered
  3. customevaporated under reduced pressure to a thick oil
  4. dissolutionThis was dissolved in toluene
  5. additionthe solution was added dropwise
  6. stirringwith stirring to petroleum ether (b.p. 40°-60° C.)
  7. customto yield a pale yellow-green solid (13 g., 90%), m.p. 110° C.

出典と根拠

ORDレコード
ord-b85a830814b44f4d86f6a52557014320
出典データセット
uspto-grants-1977_02
特許番号
US04007271

反応ノート

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