Hydrazine → HCID 12349082, compound

HRID 436446Notes

Reaction equation

HRID 436446 reaction equation
C(O[C:4]1[C:13]2[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=2)[CH2:7][CH:6]([CH3:14])[N:5]=1)C.[NH2:15][NH2:16]>>[NH:15]([C:4]1[C:13]2[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=2)[CH2:7][CH:6]([CH3:14])[N:5]=1)[NH2:16]

Participants

3

Reactant 2

HCID 9321HydrazineHCID 123490401-Ethoxy-3-methyl-3,4-dihydroisoquinoline

Product 1

HCID 12349082HCID 12349082, compound

Procedure

The reaction between 1-ethoxy-3-methyl-3,4-dihydroisoquinoline and hydrazine, which produced 1-hydrazino-3-methyl-3,4-dihydroisoquinoline, also produced a dimer, recrystallization of which from methanol-ethanol afforded 1,1'-azinobis(3-methyl-1,2,3,4-tetrahydroisoquinoline) (II: Y=CH3, Y' =Z=Z' =H) (2.2 g., m.p. 168°-171° C.).

Sources & evidence

ORD record
ord-4417d3c45f814c5cb2dc495e395b66d1
Source dataset
uspto-grants-1977_02
Patent number
US04009170

Reaction notes

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