Potassium Hydroxide → HCID 21452882, compound

HRID 436650Notes

Reaction equation

HRID 436650 reaction equation
[CH3:1][C:2]1[CH:10]=[CH:9][C:5]([C:6](Cl)=[S:7])=[CH:4][CH:3]=1.[CH2:11]([NH2:19])[CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][NH2:18].[OH-].[K+]>C(Cl)CCl>[CH3:1][C:2]1[CH:10]=[CH:9][C:5]([C:6]([NH:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][NH:19][C:6](=[S:7])[C:5]2[CH:9]=[CH:10][C:2]([CH3:1])=[CH:3][CH:4]=2)=[S:7])=[CH:4][CH:3]=1

Participants

5

Reactant 3

HCID 14797Potassium HydroxideHCID 695331,7-HeptanediamineHCID 155550054-Methylthiobenzoyl chloride

Product 1

HCID 21452882HCID 21452882, compound

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

m.p. 181°-182° C., 25.8 g., was prepared as in Example 1 using 4-methylthiobenzoyl chloride (prepared from 31 g. of 4-methylthiobenzoic acid as in Example 6) in 100 ml. of ethylene dichloride, 11.9 g. of 1,7-heptanediamine, 200 ml. of 10% aqueous potassium hydroxide solution, 500 ml. of ethylene dichloride and recrystallization from acetic acid.

Workup

  1. customof ethylene dichloride and recrystallization from acetic acid

Sources & evidence

ORD record
ord-ec271d5d0cf0403f81193e16f3c0e7d4
Source dataset
uspto-grants-1977_02
Patent number
US04009208

Reaction notes

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