Potassium Hydroxide → HCID 21452979, compound

HRID 436656Notes

Reaction equation

HRID 436656 reaction equation
[F:1][C:2]([F:14])([F:13])[O:3][C:4]1[CH:12]=[CH:11][C:7]([C:8](Cl)=[O:9])=[CH:6][CH:5]=1.[CH2:15]([NH2:27])[CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][NH2:26].[OH-:28].[K+]>C(Cl)CCl>[F:1][C:2]([F:14])([F:13])[O:3][C:4]1[CH:12]=[CH:11][C:7]([C:8]([NH:27][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][NH:26][C:8](=[O:9])[C:7]2[CH:11]=[CH:12][C:4]([O:28][C:2]([F:1])([F:13])[F:14])=[CH:5][CH:6]=2)=[O:9])=[CH:6][CH:5]=1

Participants

5

Reactant 3

HCID 14797Potassium HydroxideHCID 699661,11-UndecanediamineHCID 1421104-(Trifluoromethoxy)benzoyl Chloride

Product 1

HCID 21452979HCID 21452979, compound

Reagents, catalysts & solvents 1

HCID 111,2-DichloroethaneSolvent

Procedure

m.p. 141.5°-142.5° C., 22.2 g., was prepared as in Example 1 using 24.8 g. of 4-trifluoromethoxybenzoyl chloride in 100 ml. of ethylene dichloride, 9.3 g. of 1,11-undecanediamine, 120 ml. of 10% aqueous potassium hydroxide solution, 400 ml. of ethylene dichloride and recrystallization from acetonitrile.

Workup

  1. custom, was prepared as in Example 1 using 24.8 g
  2. customof ethylene dichloride and recrystallization from acetonitrile

Sources & evidence

ORD record
ord-5a535bcab78347c7908e47729019c2b3
Source dataset
uspto-grants-1977_02
Patent number
US04009208

Reaction notes

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