Hydrochloric Acid → 1,3,5-Triazinane-2,4,6-triimine--hydrogen chloride (1/1)

HRID 436723Notes

Reaction equation

HRID 436723 reaction equation
[ClH:1].[N:2]1[C:9]([NH2:10])=[N:8][C:6]([NH2:7])=[N:5][C:3]=1[NH2:4]>>[ClH:1].[N:2]1[C:9]([NH2:10])=[N:8][C:6]([NH2:7])=[N:5][C:3]=1[NH2:4]

Participants

3

Reactant 2

HCID 313Hydrochloric AcidHCID 7955Melamine

Product 1

HCID 5220661,3,5-Triazinane-2,4,6-triimine--hydrogen chloride (1/1)Yield 87.4%

Procedure

A charge of 500 grams of 37.7 percent hydrochloric acid was placed into a 500 milliliter, 3-neck flask fitted with a mechanical stirrer, a thermometer, and a reflux condenser. Into said reaction flask was then added 63 grams of melamine. The reaction mixture was heated to reflux and maintained at reflux for 1.5 hours. The reaction flask was then exposed to room temperature for a 16 to 17 hour period. The reaction product was filtered and washed with 300 milliliters of deionized water. The washed product was dried at 110° C. for 20 hours. Yield: 71 grams of melamine monohydrochloride (yield: 87.4%). Percent chlorine calculated: 21.8%; percent chlorine found: 22.6%.

Workup

  1. customfitted with a mechanical stirrer
  2. customreaction flask
  3. temperatureThe reaction mixture was heated
  4. temperatureto reflux
  5. temperaturemaintained
  6. temperatureat reflux for 1.5 hours
  7. filtrationThe reaction product was filtered
  8. washwashed with 300 milliliters of deionized water
  9. customThe washed product was dried at 110° C. for 20 hours

Sources & evidence

ORD record
ord-aa82d53ac1284a35b2bd7253f6e09c57
Source dataset
uspto-grants-1977_06
Patent number
US04028333

Reaction notes

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