1-Propanol → Azanium;4-ethenylbenzenesulfonate

HRID 437013Notes

Reaction equation

HRID 437013 reaction equation
C(O)CC.[CH2:5]=[CH:6][C:7]1[CH:12]=[CH:11][C:10]([S:13]([O-:16])(=[O:15])=[O:14])=[CH:9][CH:8]=1.[K+].[Cl-].[NH4+:19]>O>[CH2:5]=[CH:6][C:7]1[CH:8]=[CH:9][C:10]([S:13]([O-:16])(=[O:15])=[O:14])=[CH:11][CH:12]=1.[NH4+:19]

Participants

5

Reactant 3

HCID 10311-PropanolHCID 25517Ammonium ChlorideHCID 3083856Potassium p-vinylbenzenesulphonate

Product 1

HCID 22660406Azanium;4-ethenylbenzenesulfonate

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Conditions

Temperature
20 °C

Procedure

In 100 parts of n-propanol containing 30 wt. % of water, 10 parts of potassium p-styrenesulfonate and 7.5 parts of ammonium chloride were charged. The mixture was stirred at 20° C. for 3 hours. The reaction mixture was filtered and the filtrate was condensed and dried to obtain 8.9 parts of ammonium p-styrenesulfonate. Analysis showed that only 0.08 wt. % of K and 0.91 wt. % of Cl were included in the product.

Workup

  1. filtrationThe reaction mixture was filtered
  2. customcondensed
  3. customdried

Sources & evidence

ORD record
ord-be43fae7084840e08259a24c76219495
Source dataset
uspto-grants-1977_06
Patent number
US04029640

Reaction notes

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