HuagongsheHuagongshe Chemistry Print Report · For research reference only
Resorcinol → m-Phenylene bis[2-(4-Methylphenyl)-5-benzoxazolecarboxylate]
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Resorcinol | HCID 5054 | — |
| Reactant | Sodium Hydroxide | HCID 14798 | — |
| Reactant | 2-(4-Methylphenyl)-1,3-benzoxazole-5-carbonyl chloride | HCID 20390927 | — |
| Solvent | Water | HCID 962 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | m-Phenylene bis[2-(4-Methylphenyl)-5-benzoxazolecarboxylate] | HCID 21429976 | — |
Reaction Steps
A mixture of 1c (5.42 g. 0.02 mole), resorcinol (1.10 g., 0.02 mole), and sodium hydroxide (0.8 g., 0.02 mole) was refluxed for 3 hours in a mixture of chloroform (50 ml.) and water (15 ml.). Upon cooling a solid separated between the layers which was filtered, air-dried, and amounted to 2.43 g. (42%) of 1f. UV (CH2CH2) λ max 306 nm (52,000), ε325 = 13,000.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04029670 |
| Source dataset | uspto-grants-1977_06 |
| ORD ID | ord-910d45279aef43b4b82d080e152e6b3b |
| Source note | uspto-grants-1977_06 |