Acetone → 2-(3-Oxobutyl)cyclohexanone

HRID 437073Notes

Reaction equation

C(N[CH2:4][CH3:5])C.[C:6]1(=[O:12])[CH2:11][CH2:10][CH2:9][CH2:8][CH2:7]1.[CH3:13][C:14](C)=[O:15]>>[CH3:13][C:14](=[O:15])[CH2:4][CH2:5][CH:7]1[CH2:8][CH2:9][CH2:10][CH2:11][C:6]1=[O:12]

Participants

Reactant 3

HCID 180Acetone

HCID 7967Cyclohexanone

HCID 8021Diethylamine

Product 1

HCID 5390062-(3-Oxobutyl)cyclohexanone

Procedure

4-Diethylaminopropan-2-one prepared from acetone and diethylamine (J.C.S. 1937, 53) was reacted with cyclohexanone by the general method described in C.A. 72, 132478h to give 2-(3'-methyl-3'-oxopropyl) cyclohexanone as a colourless oil b.p. 150°/20 mm.

Sources & evidence

ORD record: ord-a983b6ad97384e6194427ffd318b678c
Source dataset: uspto-grants-1977_06
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04029668

Reaction notes

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