HRID437107

反应详情

EQUATION

反应方程式

REACTANTS

反应物

$结构：CCCCC[C@H](O)/C=C/[C@H]1[C@H](O)CC(=O)[C@@H]1C/C=C\CCCC(=O)O$

HCID5280360

未命名化合物

$结构：CCCCC(C)(C)[C@H](O)/C=C/[C@H]1[C@H](O)CC(=O)[C@@H]1C/C=C\CCCC(=O)O$

HCID5283066

7-(2-(4,4-Dimethyl-3-hydroxy-1-octenyl)-3-hydroxy-5-oxocyclopentyl)-5-heptenoic acid

C22H36O5

PRODUCTS

生成物

结构：CCCCC(C)(C)[C@H](O)/C=C/[C@H]1[C@H](O)CC(=O)[C@@H]1CCCCCCC(=O)O

HCID5283058

未命名化合物

PROCEDURE

实验过程

Further, following the procedure of Preparation 16, but using in place of the C-15 unsubstituted PGE2 -type compound of Preparation 16 and above, the 15-methyl and 15-methyl ether PGE2 -type compounds described above, there are obtained the corresponding 15-methyl and 15-methyl ether PGE1 -type compounds of either 15-epimeric configuration in both free acid and methyl ester form. Further, following the procedure of Preparation 16 but using in place of the C-16 unsubstituted PGE2 -type compound therein the 16-methyl or 16,16-dimethyl-PGE2 -type compounds described above there are obtained the corresponding 16-methyl or 16,16-dimethyl-PGE1 -type compounds of this invention. Finally, following the procedure of Preparation 16, but using the various 17-substituted phenyl PGE2 -type compounds described above there are obtained the corresponding 17-substituted phenyl-PGE1 -type compounds. The compounds in this paragraph represent the nvel PGE1 -type compounds of this invention.

WORKUP

后处理

customthe procedure of Preparation 16