Hydroxyacetonitrile → HCID 21430687, compound

HRID 437179Notes

Reaction equation

HRID 437179 reaction equation
[C:1](#[N:4])[CH2:2][OH:3].[N+:5]([C:8]1[CH:9]=[C:10]([S:14](Cl)(=[O:16])=[O:15])[CH:11]=[CH:12][CH:13]=1)([O-:7])=[O:6]>>[N+:5]([C:8]1[CH:9]=[C:10]([S:14]([O:3][CH2:2][C:1]#[N:4])(=[O:16])=[O:15])[CH:11]=[CH:12][CH:13]=1)([O-:7])=[O:6]

Participants

3

Reactant 2

HCID 7857HydroxyacetonitrileHCID 84763-Nitrobenzenesulfonyl chloride

Product 1

HCID 21430687HCID 21430687, compound

Procedure

Preparation: The technique of Example 2 is used to react glycolonitrile with m-nitrobenzenesulfonyl chloride. The product is recovered from the reaction mixture by filtration and recrystallized from ethanol. The dried product (45% conversion) is an amber solid, m.p. 66°-69° C.

Workup

  1. customPreparation
  2. filtrationThe product is recovered from the reaction mixture by filtration
  3. customrecrystallized from ethanol

Sources & evidence

ORD record
ord-37e1a7393f2e4ef3a7dad24bde78bc32
Source dataset
uspto-grants-1977_06
Patent number
US04029809

Reaction notes

Loading…