HRID437450

反应详情

EQUATION

反应方程式

REACTANTS

反应物

HCID9883

Perfluoro(methyloxirane)

C3F6O

HCID25953

Cesium fluoride

CsF

HCID53814112

2-Cyano-2,3,3,3-tetrafluoropropanoyl fluoride

C4F5NO

结构：N#CC(F)(C(F)(F)F)C(F)(F)OC(F)(C(=O)F)C(F)(F)F

HCID54075986

未命名化合物

PRODUCTS

生成物

结构：N#CC(F)(C(F)(F)F)C(F)(F)OC(F)(C(F)(F)F)C(F)(F)OC(F)(C(F)(F)F)C(F)(F)OC(F)(C(=O)F)C(F)(F)F

HCID21428441

未命名化合物

收率 77.9%

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID8925

2,5,8,11,14-Pentaoxapentadecane

C10H22O5

PROCEDURE

实验过程

By essentially the procedure of Examples 1 and 2, 7 g of cesium fluoride, 30 ml of tetraglyme, 11.5 g of perfluoro(α-cyanopropionyl) fluoride, 68.5 g of perfluoro(5-cyano-2-methyl-3-oxahexanoyl) fluoride, and 256 g of hexafluoropropylene oxide were reacted to give, in addition to the products of Examples 1 and 2, 24.1 g of perfluoro-11-cyano-2,5,8-trimethyl-3,6,9-trioxadodecanoyl fluoride, B.P. 106° C/100 mm.

来源与证据

来源类型: Open Reaction Database
ORD 记录: ord-c9ec8b09c5784cb0848b6887c56e331a
来源数据集: uspto-grants-1977_06
DOI: 10.6084/m9.figshare.5104873.v1
专利: US04031124
来源说明: uspto-grants-1977_06

反应 SMILES

[F-:1].[Cs+].[F:3][C:4]([C:12]#[N:13])([C:8]([F:11])([F:10])[F:9])[C:5]([F:7])=[O:6].[F:14][C:15]([C:31]([F:34])([F:33])[F:32])([O:19][C:20]([F:30])([F:29])[C:21]([F:28])(C#N)[C:22]([F:25])([F:24])[F:23])[C:16]([F:18])=[O:17].[F:35][C:36]([F:44])([F:43])[C:37]1([F:42])[O:41][C:38]1([F:40])[F:39]>COCCOCCOCCOCCOC>[F:14][C:15]([C:31]([F:34])([F:33])[F:32])([O:19][C:20]([F:29])([F:30])[C:21]([F:28])([C:22]([F:23])([F:25])[F:24])[O:41][C:38]([F:40])([F:39])[C:37]([F:42])([C:36]([F:44])([F:43])[F:35])[O:6][C:5]([F:1])([F:7])[C:4]([F:3])([C:12]#[N:13])[C:8]([F:9])([F:10])[F:11])[C:16]([F:18])=[O:17]