Hydroxylamine → HCID 23065677, compound

HRID 437468Notes

Reaction equation

HRID 437468 reaction equation
C1(=O)CCCCC1.O=[C:9]1[CH2:14][CH2:13][CH2:12][CH2:11][CH:10]1[CH2:15][CH:16]1[CH2:21][CH2:20][CH2:19][CH2:18][C:17]1=O.[NH2:23]O>>[CH2:21]1[C:16]2[CH:17]([NH:23][CH:9]3[C:10]([CH:15]=2)=[CH:11][CH:12]=[CH:13][CH2:14]3)[CH2:18][CH2:19][CH2:20]1

Participants

4

Reactant 3

HCID 787HydroxylamineHCID 7967CyclohexanoneHCID 37551872,2'-methanediyldicyclohexanone

Product 1

HCID 23065677HCID 23065677, compound

Procedure

Sym. octahydroacridine was prepared by converting cyclohexanone to di-(2-oxo-cyclohex-1-yl)-methane and further reacting with hydroxylamine according to the method of Gill et al (JACS 1952, 74, 4923) and was isolated as a colourless oil b.p. 110°-15°/0.5 mm. in 40% overall yield.

Sources & evidence

ORD record
ord-6a9fd37e478e40edba287784fd9df731
Source dataset
uspto-grants-1977_06
Patent number
US04031102

Reaction notes

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