Hydrogen Peroxide → HCID 13878308, compound

HRID 437993Notes

Reaction equation

HRID 437993 reaction equation
[CH3:1][S:2][CH:3]1[CH:8]([CH:9]([CH3:11])[CH3:10])[CH2:7][CH2:6][CH:5]([CH3:12])[CH2:4]1.[OH:13]O>C(O)(=O)C>[CH3:1][S:2]([CH:3]1[CH:8]([CH:9]([CH3:11])[CH3:10])[CH2:7][CH2:6][CH:5]([CH3:12])[CH2:4]1)=[O:13]

Participants

4

Reactant 2

HCID 784Hydrogen PeroxideHCID 12326071HCID 12326071, compound

Product 1

HCID 13878308HCID 13878308, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

p-Menth-3-yl methyl sulphide, prepared as in Part A (1.5 g., 8 mmoles), hydrogen peroxide (1 ml. of 30% solution) and glacial acetic acid (25 ml.) were stirred at room temperature for 17 hours. The mixture was then poured into ferrous sulphate solution and extracted with ether. The ether extracts were washed with sodium carbonate solution and then dried (MgSO4). Removal of the solvent left an oil which was purified by column chromatography and distillation to give p-menth-3-yl methyl sulphoxide, b.p. 88°/0.03 mm. (Found C, 65.3; H, 10.9. C11H22OS requires C, 65.4; H, 10.9%).

Workup

  1. extractionextracted with ether
  2. washThe ether extracts were washed with sodium carbonate solution
  3. dry with materialdried (MgSO4)
  4. customRemoval of the solvent
  5. waitleft an oil which
  6. distillationwas purified by column chromatography and distillation

Sources & evidence

ORD record
ord-8a4e73ea85b44a018ba33198ff287dd1
Source dataset
uspto-grants-1977_06
Patent number
US04032661

Reaction notes

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