Hydrogen Peroxide → HCID 21427678, compound

HRID 437997Notes

Reaction equation

HRID 437997 reaction equation
[CH2:1]([C:3]1([S:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])[CH2:8][CH2:7][CH2:6][CH2:5][CH:4]1[CH2:9][CH3:10])[CH3:2].[OH:18]O.[OH-].[Na+]>C(O)(=O)C>[CH2:1]([C:3]1([S:11]([CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH3:17])=[O:18])[CH2:8][CH2:7][CH2:6][CH2:5][CH:4]1[CH2:9][CH3:10])[CH3:2]

Participants

5

Reactant 3

HCID 784Hydrogen PeroxideHCID 14798Sodium HydroxideHCID 21427683n-Hexyl 1,2-diethylcyclohexyl sulphide

Product 1

HCID 21427678HCID 21427678, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

A mixture of n-hexyl 1,2-diethylcyclohexyl sulphide (6.5 g., 25 mmoles), glacial acetic acid (50 ml.) and hydrogen peroxide (2.7 ml. of 100 vols.) was stirred at room temperature for 20 hours. The mixture was poured into an excess of 2N sodium hydroxide and extracted with methylene chloride. The extract was washed with water and dried (MgSO4). The solvent was removed and the residual oil (6 g.) was eluted with chloroform from a silica column (Merck Kieselgel 7734). n-Hexyl 1,2-diethylcyclohexyl sulphoxide was obtained as a viscous liquid (Found: S= 11.7%. C16H32OS requires S= 11.8%).

Workup

  1. extractionextracted with methylene chloride
  2. washThe extract was washed with water
  3. dry with materialdried (MgSO4)
  4. customThe solvent was removed
  5. washthe residual oil (6 g.) was eluted with chloroform from a silica column (Merck Kieselgel 7734)

Sources & evidence

ORD record
ord-4ed7d114b01445139903a93b8572623d
Source dataset
uspto-grants-1977_06
Patent number
US04032661

Reaction notes

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