HCID 22404777, compound → HCID 22404732, compound

HRID 440677Notes

Reaction equation

HRID 440677 reaction equation
[CH3:1][C:2]1([CH3:15])[C:6](=[S:7])[C:5]2[CH:8]=[CH:9][CH:10]=[C:11]([N+:12]([O-])=O)[C:4]=2[O:3]1>C(O)(=O)C.O.[Fe]>[NH2:12][C:11]1[C:4]2[O:3][C:2]([CH3:1])([CH3:15])[C:6](=[S:7])[C:5]=2[CH:8]=[CH:9][CH:10]=1

Participants

5

Reactant 1

HCID 22404777HCID 22404777, compound

Product 1

HCID 22404732HCID 22404732, compound

Reagents, catalysts & solvents 3

HCID 23925IronCatalystHCID 176Acetic AcidSolventHCID 962WaterSolvent

Procedure

By the method of Example 1, Step E, 3.35 g (0.015 mole) of 2,3-dihydro-2,2-dimethyl-7-nitrobenzofuran-3-thione is reacted with 3.35 g (0.060 mole) of powdered iron in 50 mL of glacial acetic acid and 8 mL of water, yielding 7-amino-2,3-dihydro-2,2-dimethylbenzofuran-3-thione.

Sources & evidence

ORD record
ord-ccf5d164375e4d3da13ff7ca325b8af5
Source dataset
uspto-grants-1996_05
Patent number
US05521147

Reaction notes

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