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HRID441108

反应详情

EQUATION

反应方程式

HRID 441108 的结构方程式

REACTANTS

反应物

2
结构：OC(C(F)(F)F)C(F)(F)F
HCID13529

2H-Perfluoro-2-propanol

C3H2F6O

2 次

结构：C[C@@H]1CC[C@@H](C)P1c1ccccc1P1[C@H](C)CC[C@H]1C
HCID2734551

Methyl-duphos, (R,R)-

C18H28P2

PRODUCTS

生成物

1
结构：C[C@H]1CC[C@H](C)P1c1ccccc1P1[C@@H](C)CC[C@@H]1C
HCID2734553

Methyl-duphos, (S,S)-

C18H28P2

AUXILIARIES

试剂、催化剂与溶剂

1
结构：ClC(Cl)Cl
溶剂HCID6212

Chloroform

CHCl3

2 次

PROCEDURE

实验过程

Molar optical rotation: [Φ]D25 =-64.0° (c=3.26 mg/ml, CHCl3), [Φ]D25 =+7° (c=7.27 mg/ml (CF3)2CHOH). (R,R)-Me-DUPHOS Ligand: Molar optical rotation: [Φ]D25 =+65.0° (c= 3.26 mg/ml, CHCl3), [Φ]D25 =-7° (c=7.27 mg/ml, (CF3)2CHOH).