HuagongsheHuagongshe Chemistry Print Report · For research reference only
1,1,1,3,3,3-Hexafluoro-2-propanol → Methyl-duphos, (S,S)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 1,1,1,3,3,3-Hexafluoro-2-propanol | HCID 13529 | — |
| Reactant | Methyl-duphos, (R,R)- | HCID 2734551 | — |
| Solvent | Chloroform | HCID 6212 | — |
| Product | Methyl-duphos, (S,S)- | HCID 2734553 | — |
Reaction Steps
Molar optical rotation: [Φ]D25 =-64.0° (c=3.26 mg/ml, CHCl3), [Φ]D25 =+7° (c=7.27 mg/ml (CF3)2CHOH). (R,R)-Me-DUPHOS Ligand: Molar optical rotation: [Φ]D25 =+65.0° (c= 3.26 mg/ml, CHCl3), [Φ]D25 =-7° (c=7.27 mg/ml, (CF3)2CHOH).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05521281 |
| Source dataset | uspto-grants-1996_05 |
| ORD ID | ord-d34157fb000e4541a5a85b24468af4a3 |
| Source note | uspto-grants-1996_05 |