Diethyl Ether → HCID 131710860, compound

HRID 441360Notes

Reaction equation

HRID 441360 reaction equation
CC[O:3][CH2:4][CH3:5].[Na].[Cl:7][C:8]1[C:13]([OH:14])=[C:12]([Cl:15])[C:11]([Cl:16])=[C:10]([Cl:17])[C:9]=1[Cl:18].[Cl:19][C:20]1[C:25](CCl)=[C:24]([Cl:28])[C:23]([Cl:29])=[C:22]([Cl:30])[C:21]=1[Cl:31]>COCCO>[Cl:7][C:8]1[C:5]([CH2:4][OH:3])=[C:12]([Cl:15])[C:11]([Cl:16])=[C:10]([Cl:17])[C:9]=1[Cl:18].[Cl:7][C:8]1[C:13]([O:14][C:25]2[C:24]([Cl:28])=[C:23]([Cl:29])[C:22]([Cl:30])=[C:21]([Cl:31])[C:20]=2[Cl:19])=[C:12]([Cl:15])[C:11]([Cl:16])=[C:10]([Cl:17])[C:9]=1[Cl:18]

Participants

5

Reactant 3

HCID 3283Diethyl EtherHCID 96677Benzene, pentachloro(chloromethyl)-HCID 87060549131-52-2

Product 1

HCID 131710860HCID 131710860, compound

Reagents, catalysts & solvents 1

HCID 80192-MethoxyethanolSolvent

Procedure

This ether was prepared by reacting, by the procedure of Example 1, 60 g (about 0.2 mole) of pentachlorophenol sodium, 400 ml of methyl glycol and 60 g (about 0.2 mole) of pentachlorobenzyl chloride. In this case, the ether precipitated between 45° and 60° C. After the reaction mixture has cooled, the product that had separated in a sago-like form was removed by suction filtering and worked up as described above. 88 g (83%) having a melting point of 264° to 266° C. was obtained.

Workup

  1. customIn this case, the ether precipitated between 45° and 60° C
  2. temperatureAfter the reaction mixture has cooled
  3. customthe product that had separated in a sago-like form
  4. customwas removed by suction
  5. filtrationfiltering
  6. customwas obtained

Sources & evidence

ORD record
ord-b8df57cc77404bc59a286f62ac3947ca
Source dataset
uspto-grants-1977_08
Patent number
US04039587

Reaction notes

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