Sodium Iodide → HCID 12665791, compound

HRID 441960Notes

Reaction equation

HRID 441960 reaction equation
COS([O-])(=O)=O.[Cl:7][C:8]1[N:9]([CH3:20])[N+:10]([CH3:19])=[C:11]([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:12]=1.[I-:21].[Na+]>>[I-:21].[Cl:7][C:8]1[N:9]([CH3:20])[N+:10]([CH3:19])=[C:11]([C:13]2[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=2)[CH:12]=1

Participants

3

Reactant 2

HCID 5238Sodium IodideHCID 12665764HCID 12665764, compound

Product 1

HCID 12665791HCID 12665791, compound

Procedure

To an aqueous solution of 3-chloro-1,2-dimethyl-5-phenylpyrazolium methyl sulfate is added a saturated aqueous solution of sodium iodide at 5° C. A copious precipitate is formed and filtered off. The solid is dissolved in methylene chloride and precipitated with diethyl ether to yield almost white crystals mp 162° to 164° C.

Workup

  1. customA copious precipitate is formed
  2. filtrationfiltered off
  3. dissolutionThe solid is dissolved in methylene chloride
  4. customprecipitated with diethyl ether

Sources & evidence

ORD record
ord-7bcd08afd7d445c483b35910ebaa1f54
Source dataset
uspto-grants-1977_08
Patent number
US04044013

Reaction notes

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