3-Phenylprop-2-En-1-Ol → 3-phenyl-2-propenyl nitro(tetrahydro-2H-1,3-thiazin-2-ylidene)acetate

HRID 442303Notes

Reaction equation

HRID 442303 reaction equation
[N+:1]([C:4](=[C:9]1[NH:14][CH2:13][CH2:12][CH2:11][S:10]1)[C:5]([O:7][CH3:8])=[O:6])([O-:3])=[O:2].C(O)[CH:16]=[CH:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1>>[N+:1]([C:4](=[C:9]1[NH:14][CH2:13][CH2:12][CH2:11][S:10]1)[C:5]([O:7][CH2:8][CH:16]=[CH:17][C:18]1[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=1)=[O:6])([O-:3])=[O:2]

Participants

3

Reactant 2

HCID 3083-Phenylprop-2-En-1-OlHCID 71400745Methyl nitro(1,3-thiazinan-2-ylidene)acetate

Product 1

HCID 737915503-phenyl-2-propenyl nitro(tetrahydro-2H-1,3-thiazin-2-ylidene)acetate

Procedure

2 was prepared as a yellow solid, m.p.: 115°-116°, from 1A and cinnamyl alcohol by the procedures described in Example 1.

Sources & evidence

ORD record
ord-fa1346b82f9d406f9976962366a919cb
Source dataset
uspto-grants-1977_08
Patent number
US04045434

Reaction notes

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