Sodium Iodide → HCID 14662926, compound

HRID 442457Notes

Reaction equation

HRID 442457 reaction equation
[I-].[Na+].[CH3:3][O:4][CH:5]([O:12][CH3:13])[C:6](=[O:11])/[CH:7]=[CH:8]\[CH2:9][CH3:10]>C(O)(=O)C>[CH3:13][O:12][CH:5]([O:4][CH3:3])[C:6](=[O:11])/[CH:7]=[CH:8]/[CH2:9][CH3:10]

Participants

4

Reactant 2

HCID 5238Sodium IodideHCID 57417966HCID 57417966, compound

Product 1

HCID 14662926HCID 14662926, compound

Reagents, catalysts & solvents 1

HCID 176Acetic AcidSolvent

Procedure

The crude product produced in Example II is dissolved in 6 ml of acetic acid with 0.1 g of sodium iodide. By GLC analysis on Carbowax(polyethylene glycol) it is clear that the 1,1-dimethoxy-cis-3-hexene-2-one is converted to a new material of later retention time. After one-half hour less than 5 percent of "cis" material remains.

Workup

  1. waitAfter one-half hour less than 5 percent of "cis" material remains

Sources & evidence

ORD record
ord-5f653d0398c944e086f1b4e44a572831
Source dataset
uspto-grants-1977_08
Patent number
US04045497

Reaction notes

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