Potassium Carbonate → HCID 21415172, compound

HRID 442513Notes

Reaction equation

HRID 442513 reaction equation
C(O)(=O)C(O)=O.[CH2:7]([S:14][CH:15]([C:24]1[CH:29]=[CH:28][C:27]([Cl:30])=[CH:26][CH:25]=1)[CH2:16][CH2:17][CH2:18][N:19]1[CH:23]=[CH:22][N:21]=[CH:20]1)[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13].C(=O)([O-])[O-].[K+].[K+]>ClCCl>[CH2:7]([S:14][CH:15]([C:24]1[CH:29]=[CH:28][C:27]([Cl:30])=[CH:26][CH:25]=1)[CH2:16][CH2:17][CH2:18][N:19]1[CH:23]=[CH:22][N:21]=[CH:20]1)[CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]

Participants

4

Reactant 2

HCID 11430Potassium CarbonateHCID 21415171HCID 21415171, compound

Product 1

HCID 21415172HCID 21415172, compound

Reagents, catalysts & solvents 1

HCID 6344DichloromethaneSolvent

Procedure

1-[4-Heptylthio-4-(4-chlorophenyl)butyl]imidazole oxalate (2.0 g.) in 100 ml. of dichloromethane was shaken with excess dilute potassium carbonate solution until the salt was completely dissolved. The organic layer was then separated, washed twice with water, dried over magnesium sulfate and evaporated to yield 1-[4-heptylthio-4-(4-chlorophenyl)butyl]imidazole as an oil.

Workup

  1. dissolutionwas completely dissolved
  2. customThe organic layer was then separated
  3. washwashed twice with water
  4. dry with materialdried over magnesium sulfate
  5. customevaporated

Sources & evidence

ORD record
ord-0701acdc4b20472f81aa36e06296b863
Source dataset
uspto-grants-1977_08
Patent number
US04045568

Reaction notes

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