HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium amide → HCID 21415007, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium amide | HCID 24533 | — |
| Reactant | Bromomethylcyclopropane | HCID 81503 | — |
| Reactant | 2-[(9,10-Methanoanthracen-9(10H)-yl)methyl]morpholine | HCID 21415027 | — |
| Solvent | Benzene | HCID 241 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 21415007 | HCID 21415007 | — |
Reaction Steps
A mixture of 9-(2-morpholinylmethyl)-9,10-dihydro-9,10-methanoanthracene (50 mg), cyclopropylmethyl bromide (40 mg) and sodium amide (15 mg) in dry benzene was refluxed for 10 hours. The reaction mixture was diluted with benzene and water. The benzene layer was washed with water, dried over anhydrous sodium sulfate and evaporated to dryness to give 9-(4-cyclopropylmethyl-2-morpholinylmethyl)-9,10-dihydro-9,10-methanoanthracene, M.P. 88° - 90° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04045560 |
| Source dataset | uspto-grants-1977_08 |
| ORD ID | ord-313514674ee04de6a85b9612e1bfaf9c |
| Source note | uspto-grants-1977_08 |