Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Allylamine | HCID 7853 | — |
| Reactant | 1,3,5,7-Tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxane | HCID 75706 | — |
| Reactant | 1,1,1,5,5,5-Hexamethyl-3-phenyltrisiloxane | HCID 71357599 | — |
| Product | HCID 53914816 | HCID 53914816 | 86% |
Reaction Steps
A 100 ml flask was equipped with a magnetic stirrer, reflux condenser, pot thermometer, and a sampling port. The flask was loaded with 30 g (0.105 mole ) of bis(trimethylsiloxy)phenylsilane and 6 g (0.105 ) mole of allylamine and heated to reflux (79° C.). 180 μl of 3% Pt complexed with tetravinyltetramethylcyclotetrasiloxane were added. The mixture was heated to 125° C. and held for one hour. Thirty one grams (86%) of 3-aminopropyl-bis(trimethylsiloxy)phenylsilane were produced. None of the isomeric 2-aminopropyl-bis(trimethylsiloxy)phenylsilane was formed.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US05892084 |
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| Source dataset | uspto-grants-1999_04 |
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| ORD ID | ord-0b59672cf7714d9b886471483a2cc588 |
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| Source note | uspto-grants-1999_04 |
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