Allylamine → HCID 53914816, compound

HRID 443074Notes

Reaction equation

HRID 443074 reaction equation
[CH3:1][Si:2]([CH3:17])([CH3:16])[O:3][SiH:4]([O:11][Si:12]([CH3:15])([CH3:14])[CH3:13])[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1.[CH2:18]([NH2:21])[CH:19]=[CH2:20].C([Si]1(C)O[Si](C=C)(C)O[Si](C=C)(C)O[Si](C=C)(C)O1)=C>>[NH2:21][CH2:18][CH2:19][CH2:20][Si:4]([O:11][Si:12]([CH3:15])([CH3:14])[CH3:13])([O:3][Si:2]([CH3:17])([CH3:16])[CH3:1])[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7][CH:6]=1

Participants

4

Reactant 3

HCID 7853AllylamineHCID 757061,3,5,7-Tetramethyl-1,3,5,7-tetravinylcyclotetrasiloxaneHCID 713575991,1,1,5,5,5-Hexamethyl-3-phenyltrisiloxane

Product 1

HCID 53914816HCID 53914816, compoundYield 86%

Conditions

Temperature
79 °C

Procedure

A 100 ml flask was equipped with a magnetic stirrer, reflux condenser, pot thermometer, and a sampling port. The flask was loaded with 30 g (0.105 mole ) of bis(trimethylsiloxy)phenylsilane and 6 g (0.105 ) mole of allylamine and heated to reflux (79° C.). 180 μl of 3% Pt complexed with tetravinyltetramethylcyclotetrasiloxane were added. The mixture was heated to 125° C. and held for one hour. Thirty one grams (86%) of 3-aminopropyl-bis(trimethylsiloxy)phenylsilane were produced. None of the isomeric 2-aminopropyl-bis(trimethylsiloxy)phenylsilane was formed.

Workup

  1. customA 100 ml flask was equipped with a magnetic stirrer
  2. temperaturereflux condenser
  3. temperatureheated
  4. additionwere added
  5. temperatureThe mixture was heated to 125° C.

Sources & evidence

ORD record
ord-0b59672cf7714d9b886471483a2cc588
Source dataset
uspto-grants-1999_04
Patent number
US05892084

Reaction notes

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