HuagongsheHuagongshe Chemistry Print Report · For research reference only
Hydrazine → 5-Methylthio-2-aminobenzoic acid hydrazide
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Hydrazine | HCID 9321 | — |
| Reactant | 6-methylsulfanyl-1H-benzo[d][1,3]oxazine-2,4-dione | HCID 12713255 | — |
| Solvent | Water | HCID 962 | — |
| Product | 5-Methylthio-2-aminobenzoic acid hydrazide | HCID 12713237 | — |
Reaction Steps
6-methylthio-2H-3,1-benzoxazine-2,4-(1H)-dione (25.11 g; 0.72 mole) is added to a cold solution of 54.4% hydrazine (75 ml) in water (75 ml). After stirring at room temperature overnight, the while solid is filtered, washed with cold water and dried. Yield 21.3 g; mp 124°-127°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04261996 |
| Source dataset | uspto-grants-1981_04 |
| ORD ID | ord-f2b76511e3944de0b55d8c5008551fd3 |
| Source note | uspto-grants-1981_04 |