Ethylenediamine → N,N'-bis[2,4-bis(2,2,6,6-tetramethyl-4-piperidylamino)-1,3,5-triazin-6-yl]ethylenediamine

HRID 444316Notes

Reaction equation

HRID 444316 reaction equation
Cl[C:2]1[N:7]=[C:6]([NH:8][CH:9]2[CH2:14][C:13]([CH3:16])([CH3:15])[NH:12][C:11]([CH3:18])([CH3:17])[CH2:10]2)[N:5]=[C:4]([NH:19][CH:20]2[CH2:25][C:24]([CH3:27])([CH3:26])[NH:23][C:22]([CH3:29])([CH3:28])[CH2:21]2)[N:3]=1.[CH2:30]([NH2:33])[CH2:31][NH2:32].[OH-].[Na+]>C1(C)C(C)=CC=CC=1>[CH3:26][C:24]1([CH3:27])[CH2:25][CH:20]([NH:19][C:4]2[N:5]=[C:6]([NH:8][CH:9]3[CH2:14][C:13]([CH3:16])([CH3:15])[NH:12][C:11]([CH3:18])([CH3:17])[CH2:10]3)[N:7]=[C:2]([NH:32][CH2:31][CH2:30][NH:33][C:2]3[N:3]=[C:4]([NH:19][CH:20]4[CH2:25][C:24]([CH3:27])([CH3:26])[NH:23][C:22]([CH3:29])([CH3:28])[CH2:21]4)[N:5]=[C:6]([NH:8][CH:9]4[CH2:10][C:11]([CH3:18])([CH3:17])[NH:12][C:13]([CH3:16])([CH3:15])[CH2:14]4)[N:7]=3)[N:3]=2)[CH2:21][C:22]([CH3:29])([CH3:28])[NH:23]1

Participants

5

Reactant 3

HCID 3301EthylenediamineHCID 14798Sodium HydroxideHCID 214680172-Chloro-4,6-bis(2,2,6,6-tetramethyl-4-piperidylamino)-1,3,5-triazine

Product 1

HCID 23464889N,N'-bis[2,4-bis(2,2,6,6-tetramethyl-4-piperidylamino)-1,3,5-triazin-6-yl]ethylenediamine

Reagents, catalysts & solvents 1

HCID 7237O-XyleneSolvent

Procedure

42.3 (0.1 mole) of 2-chloro-4,6-bis(2,2,6,6-tetramethyl-4-piperidylamino)-1,3,5-triazine (prepared according to example 2A), 3 g (0.05 moles) of ethylenediamine, 4 g of sodium hydroxide and 150 ml of xylene were boiled for 16 hours under stirring.

Sources & evidence

ORD record
ord-2b067e7060024897ab2b12d59c2242ee
Source dataset
uspto-grants-1981_04
Patent number
US04263434

Reaction notes

Loading…