HuagongsheHuagongshe Chemistry Print Report · For research reference only
Lithium Hydroxide → HCID 12912741, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Lithium Hydroxide | HCID 3939 | — |
| Reactant | Dimethylformamide | HCID 6228 | — |
| Reactant | p-Chlorothiophenol | HCID 7815 | — |
| Reactant | 5-Chloro-2-nitropyridine | HCID 259806 | — |
| Solvent | Water | HCID 962 | — |
| Product | HCID 12912741 | HCID 12912741 | — |
Reaction Steps
2-Nitro-5-chloropyridine (9.5 grams), 4-chlorothiophenol (8.7 grams), and lithium hydroxide (4 grams) were mixed in 100 ml. of DMF and the reaction mixture was stirred overnight (about 18 hours) at room temperature. The reaction mixture was then poured into water and the product separated by filtration and crystallized from ethanol-hexanes, yield, 10.0 grams, m.p., 96°-98° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04264605 |
| Source dataset | uspto-grants-1981_04 |
| ORD ID | ord-59219e31105d4d478d72800c39063248 |
| Source note | uspto-grants-1981_04 |