HCID 86617058, compound → HCID 86617057, compound

HRID 446691Notes

Reaction equation

HRID 446691 reaction equation
[Cl:1][C:2]1[C:10]2[C:9]3[C:11]([Cl:17])=[C:12]([Cl:16])[C:13]([Cl:15])=[CH:14][C:8]=3[O:7][C:6]=2[C:5]([N+:18]([O-])=O)=[C:4]([Cl:21])[C:3]=1[Cl:22]>C(O)C>[Cl:1][C:2]1[C:10]2[C:9]3[C:11]([Cl:17])=[C:12]([Cl:16])[C:13]([Cl:15])=[CH:14][C:8]=3[O:7][C:6]=2[C:5]([NH2:18])=[C:4]([Cl:21])[C:3]=1[Cl:22]

Participants

3

Reactant 1

HCID 86617058HCID 86617058, compound

Product 1

HCID 86617057HCID 86617057, compound

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

The corresponding amine was prepared by reducing 1,2,3,7,8,9-hexachloro-4-nitrodibenzofuran with 1.8 mmol of NaSH in 5 ml of ethanol. The resulting 1,2,3,7,8,9-hexachloro-4-aminodibenzofuran was isolated by extracting with five times 30 ml of diethyl ether. The resulting solution was washed twice with 10 ml of water and dried over magnesium sulfate. Subsequently, the amine was removed from the desiccant and isolated again.

Sources & evidence

ORD record
ord-e9c3a362355944d1b64efbf09a637e59
Source dataset
uspto-grants-2013_07
Patent number
US08481327B2

Reaction notes

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