Benzophenone → HCID 68797400, compound

HRID 450905Notes

Reaction equation

[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH:8]=[C:9]([O:14][CH3:15])[C:10]=1[CH:11]([CH3:13])[CH3:12])[CH2:6]Br.[C:16]([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)(=[O:23])[C:17]1[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=1>>[CH3:1][O:2][C:3]1[CH:4]=[C:5]([CH2:6][C:16]([C:17]2[CH:22]=[CH:21][CH:20]=[CH:19][CH:18]=2)([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[OH:23])[CH:8]=[C:9]([O:14][CH3:15])[C:10]=1[CH:11]([CH3:13])[CH3:12]

Participants

Reactant 2

HCID 3102Benzophenone

HCID 66842814443982-73-8

Product 1

HCID 68797400HCID 68797400, compound

Procedure

This compound was prepared from 3,5-dimethoxy-4-i-propylbenzyl bromide obtained in example 6(b), Mg and benzophenone by the same procedure as described in example 1 (b). 1HNMR (CDCl3, ppm): δ 1.24 (d, J=7.1 Hz, 6H), 3.3-3.5 (m, 1H), 3.56 (s, 6H), 3.72 (d, J=15.4 Hz, 2H), 6.04 (s, 2H), 7.2-7.7 (m, 10H).

Sources & evidence

ORD record: ord-4a95d3069fc54a30b9cf36cd76e9b2f9
Source dataset: uspto-grants-2013_07
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08487009B2

Reaction notes

Loading…