HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium methanethiolate → HCID 18439593, compound
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium methanethiolate | HCID 4378561 | — |
| Reactant | HCID 18439592 | HCID 18439592 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | HCID 18439593 | HCID 18439593 | — |
Reaction Steps
44.6 g (0.14 mol) of methyl 4-methylsulfonyl-3-fluoro-2-bromomethylbenzoate were dissolved in THF. 10.58 g (0.15 mol) of sodium thiomethoxide were added at RT and the mixture was then heated under reflux for 5 h. It was then poured onto ice-water and extracted with EE. The combined organic phases were dried over MgSO4 and concentrated to completion.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US07189679B2 |
| Source dataset | uspto-grants-2007_03 |
| ORD ID | ord-10b24d3bd4664d03923a67acd1fce411 |
| Source note | uspto-grants-2007_03 |