Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Hydrazine | HCID 9321 | — |
| Reactant | 8-Quinolinesulfonyl chloride | HCID 29220 | — |
| Solvent | Methanol | HCID 887 | — |
| Product | HCID 747844 | HCID 747844 | 71.7% |
Reaction Steps
A 500 ml Erlenmeyer flask equipped with a magnetic stirrer and a thermometer is charged with 200 ml of methanol and 3.40 g (0.10 mol) of 95% hydrazine. The solution is cooled to 5° C, and 11.38 g (0.05 mol) of 8-quinolinesulfonyl chloride is added in small portions at a rate such that the reaction temperature does not exceed 15° C. After the reaction is complete, the solution is allowed to warm slowly to room temperature. The precipitating solid is filtered off to give 8.00 g of 8-quinolinesulfonyl hydrazine (C9H9N3O2S), m.p. 135°-137° C.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US04061639 |
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| Source dataset | uspto-grants-1977_12 |
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| ORD ID | ord-73064a78213e4e018a439d753566ba47 |
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| Source note | uspto-grants-1977_12 |
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