Triphenylphosphine → HCID 20494866, compound

HRID 460947Notes

Reaction equation

HRID 460947 reaction equation
[CH3:1][C:2]1[S:3][C:4]([CH3:10])=[C:5]([CH3:9])[C:6]=1[CH2:7][Cl:8].[C:11]1([P:17]([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>C1C=CC=CC=1>[Cl-:8].[CH3:1][C:2]1[S:3][C:4]([CH3:10])=[C:5]([CH3:9])[C:6]=1[CH2:7][P+:17]([C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1)([C:24]1[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=1)[C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1

Participants

4

Reactant 2

HCID 11776TriphenylphosphineHCID 20285666HCID 20285666, compound

Product 1

HCID 20494866HCID 20494866, compound

Reagents, catalysts & solvents 1

HCID 241BenzeneSolvent

Procedure

33.2 G. of 2,4,5-trimethyl-3-chloromethyl-thiophene and 55.0 g. of triphenyl phosphine were dissolved in 200 ml. of benzene. The resulting mixture was refluxed overnight under argon and then cooled to room temperature. The precipitated white phosphonium salt which formed was collected by filtration, washed several times with cold benzene and dried at 80° C. under high vacuum to yield (2,4,5-trimethyl-3-thenyl)triphenyl phosphonium chloride, m.p. 236°-237° C.

Workup

  1. temperatureThe resulting mixture was refluxed overnight under argon

Sources & evidence

ORD record
ord-6a9881a844144c63bcc21cc050771cfe
Source dataset
uspto-grants-1977_12
Patent number
US04061656

Reaction notes

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