Hydrochloric Acid → 2-(6-Carboxyoctyl)-2-cyclopentenone

HRID 461245Notes

Reaction equation

HRID 461245 reaction equation
[C:1]([CH:4]([CH2:16][CH3:17])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]1[C:11](=[O:15])[CH2:12][CH2:13][CH:14]=1)([OH:3])=[O:2].C1C(/C=N/O)=CC=[N+](C[N+]2C=CC(/C=N/O)=CC=2)C=1.[Br-].[Br-].Cl>CC(C)=O>[C:1]([CH:4]([CH2:16][CH3:17])[CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][C:10]1[C:11](=[O:15])[CH2:12][CH2:13][CH:14]=1)([OH:3])=[O:2]

Participants

4

Reactant 2

HCID 313Hydrochloric AcidHCID 178442627HCID 178442627, compound

Product 1

HCID 217678162-(6-Carboxyoctyl)-2-cyclopentenone

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

Treatment of 2-(6-carboxyoctyl)-2-cyclopentenone methoxime (Example 29) with acetone and 2N hydrochloric acid in the manner described in Example 22 gives a light yellow oil.

Workup

  1. customgives a light yellow oil

Sources & evidence

ORD record
ord-f1a6642eaec64c27aebdbd98d92b1ac8
Source dataset
uspto-grants-1977_12
Patent number
US04061672

Reaction notes

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