1,6-Hexanediol → HCID 88826255, compound

HRID 461313Notes

Reaction equation

HRID 461313 reaction equation
[CH2:1]([O:3][P:4]([CH:9]([CH2:15][C:16]([O:18][CH2:19][CH2:20][OH:21])=[O:17])[C:10]([O:12][CH2:13][CH3:14])=[O:11])([O:6][CH2:7][CH3:8])=[O:5])[CH3:2].[C:22](O)(=O)/[CH:23]=[CH:24]/[C:25](O)=O.C(O)CCCCCO.[PH2](O)=O.C(OP(OCC)OCC)C.[P]>>[CH2:7]([O:6][P:4]([CH:9]([CH2:15][C:16]([O:18][CH2:19][CH:20]([OH:21])[CH2:22][CH2:23][CH2:24][CH3:25])=[O:17])[C:10]([O:12][CH2:13][CH3:14])=[O:11])([O:3][CH2:1][CH3:2])=[O:5])[CH3:8]

Participants

7

Reactant 6

HCID 123741,6-HexanediolHCID 31215Triethyl phosphite2×HCID 444972Fumaric AcidHCID 4124402Phosphinic AcidHCID 5462309PhosphorusHCID 85929651HCID 85929651, compound

Product 1

HCID 88826255HCID 88826255, compound

Procedure

The procedures according to Example 1 were repeated using similar apparatus and under essentially similar conditions allowing for the differences in quantities of materials employed. In this example, for the materials of Example 1, 1 mol fumaric acid, 1 mol of 1,6-hexane diol, 0.1% of hypophosphorous acid and 1 mol of triethylphosphite were employed. The product of the reaction had analytical values for acid value, hydroxyl, free triethylphosphite and phosphorus content comparable to those reported in Example 1.

Sources & evidence

ORD record
ord-979dd6d6da914ad1b8a0fe7a862ddc2a
Source dataset
uspto-grants-1977_12
Patent number
US04062829

Reaction notes

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